Energy is needed in every sector, due to the high demand for energy in the World today, crude oil; one of the largest sources is being heavily relied on. To fulfill the energy demand, crude oil production is increasing every year. According to World crude oil demand and supply source nearly 26.28 billion barrels of crude oil is produced each year whereas, the consumption is 28.57 billion barrels per year. The deficient amount is generated from other sources such as Solar, Wind, Hydrogen, Geothermal and other alternate sources. Petroleum derives from crude oil; petroleum is then is used for daily transportation use and production of plastics for daily use. In 2008, 245 million tons of plastics were produced worldwide. After daily use the plastics becomes abundant and occupies landfill and remain in the landfill for a long period of time. The exposure of these waste plastics to air creates many problems to the environment. A simple thermolysis and economically viable process to remove these waste plastics from landfill and converting them into liquid hydrocarbon mixtures fuel has been developed and temperature range 25 to 390 ºC, which is environmental friendly. The produced fuel contains long carbon chain lengths C3–C27 determine by GC/MS, FT-IR analysis result showed produced fuel functional group band energy and DSC analysis result showed fuel heat enthalpy value and ASTM test result showed low sulfur contents resulting high performance and environmentally friendly at the same time. Produce fuel could be use as internal combustion engine, feed for feed stock refinery or electricity generation feed for power plants. By using this technology can be solved waste plastic problem as well as environmental problems and reduce some percentage of foreign oil dependency and boost up alternative energy sector.